RNAregulatory exosome complicated confers cell emergency to advertise erythropoiesis

5 %, and the addition of the sludge (≤5.0 %) into raw meal could not induce further environment hazards.In this work, modified chitosan flocculants (MCS) was synthesized by using chitosan (CS), acrylamide, cationic monomers and hydrophobic monomers via low-pressure UV-initiated copolymerization. The flocculation performance of MCS was evaluated in emulsified oily wastewater treatment. The effect of cationic and hydrophobic structure on oil removal was studied, and the interactions between these functional groups and the components in oil were also analyzed. Results suggested that MCS flocculants exhibited excellent oil removal efficiency in a wide pH range (2.0‒10). The flocculation efficiency of 91 % was achieved at the dosages of 0.6 mL/L (6 mg/L). During pH of 2.0-10, the optimal cationic and hydrophobic monomer was DMC and VT, respectively. Silane groups were favorable for oil removal than the other hydrophobic structures. The cationic groups expanded the optimal pH range of MCS in flocculation, whereas hydrophobic groups considerably reduced the dosage of MCS. The experimental results showed that alkane, cyclic aromatic hydrocarbon compounds in oil can be easily removed by using MC4, whereas cycloalkanes compounds was effectively removed by MC6 and MC7 because of preferable demulsification capacity, and the hydrophobic interaction, interfacial adsorption and electrostatic attraction played the dominant in flocculation. Thus, the synthesized MCS is favorable for emulsified oily wastewater treatment.Current understanding of perfluorooctanoic acid (PFOA) transport in unsaturated porous media is still limited with significant variability in solution chemistry. Column experiments were conducted to systematically evaluate the impacts of ionic strength (1.5-30 mM) and cation type (Na+ and Ca2+) on PFOA transport in unsaturated quartz sand. The results showed that an increase in ionic strength (1.5-30 mM) led to greater PFOA retardation in unsaturated columns. Meanwhile, Ca2+ caused more PFOA retardation than Na+ at the same unsaturated conditions. These findings were supported by bubble column experiments, which indicated greater PFOA adsorption at the air-water interface with increasing ionic strength or in the presence of Ca2+ in comparison to Na+. Furthermore, the air-water interfacial (AWI) adsorption coefficients calculated from surface tension isotherms also increased with increasing ionic strength or in the presence of Ca2+ in comparison to Na+. These results clearly confirm that higher ionic strength or cation valence significantly promoted PFOA adsorption at the air-water interface, and thus caused greater PFOA retardation during transport in unsaturated porous media. This work points out the importance of considering solution ionic strength and cation type in assessing the transport behavior of PFOA in unsaturated porous media.In this work, the incorporation of Fe-bearing sludge-derived biochar greatly enhanced both biotic and abiotic reduction of nitrobenzene (NB) to aniline, which was attributed to the concomitant microbial dissimilatory iron reduction. Biogenic Fe(II) produced by Geobacter sulfurreducens dominated the anaerobic reduction of NB following the pseudo-first-order kinetic. Besides, the increase of pyrolysis temperature from 600 to 900 ℃ to generate biochar resulted in an accelerated removal rate of NB in Geobacter-biochar combined system. The morphology and structural characterization of biochar with G. sulfurreducens confirmed the formation of conductive bacteria-biochar aggregates. Electrochemical measurements suggested the presence of graphitized domains and quinone-like moieties in biochar as redox-active centers, which might play an important role in accelerating electron transfer for microbial dissimilatory iron reduction and NB degradation. This study provides a feasible way of using Fe-bearing sludge as a valuable feedstock for biochar generation and its application with electrochemically active bacteria for the bioremediation of nitroaromatic compounds-polluted wastewater.To intensively investigate chemical kinetic behaviors at the initial stage of CH4/H2/air mixture thoroughly, the density functional theory (CAMB3LYP/6-31 G) and a detailed mechanism (GRI-Mech3.0) were used to obtain kinetic and thermodynamic parameters. The reaction paths during the explosion process were analyzed, and the reaction rates of elementary reactions were compared with different ratios of CH4/H2/air mixture. The key reactions at the initiation stage of CH4/H2/air mixture explosion were determined, and their configurations were optimized. The reaction mechanism, reaction channel and configuration parameters of key reactions were obtained, which was verified by the intrinsic reaction coordinate (IRC) theory. Results show that H2 addition increases the laminar burning velocity, while it shortens the ignition delay time of H2/CH4/air mixture. The addition of hydrogen greatly accelerated the explosion reaction from sample 1 to sample 4. Moreover, CH4 still plays a key role at the chain initiation stage in H2/CH4/air mixture system; the addition of H2 would not compete with CH4 for triggering the explosion reaction, nor will it suppress the explosion of CH4. H2 could not replace or take precedence over the chain branching reactant (CH2O) of CH4 explosion to react with O2. Besides, H2 takes precedence over CH4 in the process of chain transfer after the chain reaction beginning, although CH4 has a distinct advantage in the chain initiation stage. The present results can provide theoretical guidance for the prevention and control of gas explosion, which may effectively reduce the explosion hazards.A cocultivation of the Pseudomonas mendocina with Actinomucor elegans was developed and investigated to improve the biodegradation of polylactic acid/polybutylene adipate-co-terephthalate (PLA/PBAT). And the coculture system could produce an efficient PLA/PBAT-degrading enzymes system to degrade PLA/PBAT films. The results showed that the protease activity (11.50 U/mL) and lipase activity (40.46 U/mL) of the coculture exceeded that of the monoculture (P. mendocina of 7.31 U/mL, A. elegans of 32.47 U/mL). The degradation rate of PLA/PBAT films using the coculture system was 18.95 wt% within 5 days, which was considerably higher than that of P. mendocina (12.94 wt%) and A. elegans (9.27 wt%) individually, suggesting that P. mendocina and A. elegans had synergistic degradation. In addition, P. selleck kinase inhibitor mendocina and A. elegans could secrete proteases and lipases, respectively, which could catalyze the ester bonds of PLA1 and PBAT in PLA/PBAT films, respectively, and hydrolyze them into different monomers and oligomers as nutrition sources.